The Passivity of Metals | Nature

The Passivity of Metals | Nature

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ABSTRACT CHROMIUM, iron, cobalt, nickel, copper, and bismuth are said to exhibit the phenomenon of passivity. These metals have electrode potentials varying from about Fe = + 0.06 to Bi = −0.67 volt—that is, they are not very electro-positive. They also all exhibit dual valencies. This suggests that passivity may be due to an electrical double layer on the surface of the metal, especially when it is remembered that an anode of iron becomes passive in nitric acid of sufficient concentration. Access through your institution Buy or subscribe This is a preview of subscription content, access via your institution ACCESS OPTIONS Access through your institution Subscribe to this journal Receive 51 print issues and online access $199.00 per year only $3.90 per issue Learn more Buy this article * Purchase on SpringerLink * Instant access to full article PDF Buy now Prices may be subject to local taxes which are calculated during checkout ADDITIONAL ACCESS OPTIONS: * Log in * Learn about institutional subscriptions * Read our FAQs * Contact customer support SIMILAR CONTENT BEING VIEWED BY OTHERS CORROSION INHIBITION OF COPPER IN FERRIC CHLORIDE SOLUTIONS WITH ORGANIC INHIBITORS Article Open access 18 November 2020 CHEMICAL, ELECTROCHEMICAL, AND QUANTUM INVESTIGATION INTO THE USE OF AN ORGANOPHOSPHORUS DERIVATIVE TO INHIBIT COPPER CORROSION IN ACIDIC ENVIRONMENTS Article Open access 18 May 2024 MICROBIALLY MEDIATED METAL CORROSION Article 21 June 2023 AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Bedford Modern School, W. HUGHES Authors * W. HUGHES View author publications You can also search for this author inPubMed Google Scholar RIGHTS AND PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE HUGHES, W. The Passivity of Metals. _Nature_ 106, 692–693 (1921). https://doi.org/10.1038/106692c0 Download citation * Published: 01 January 1921 * Issue Date: 27 January 1921 * DOI: https://doi.org/10.1038/106692c0 SHARE THIS ARTICLE Anyone you share the following link with will be able to read this content: Get shareable link Sorry, a shareable link is not currently available for this article. Copy to clipboard Provided by the Springer Nature SharedIt content-sharing initiative

ABSTRACT CHROMIUM, iron, cobalt, nickel, copper, and bismuth are said to exhibit the phenomenon of passivity. These metals have electrode potentials varying from about Fe = + 0.06 to Bi =


−0.67 volt—that is, they are not very electro-positive. They also all exhibit dual valencies. This suggests that passivity may be due to an electrical double layer on the surface of the


metal, especially when it is remembered that an anode of iron becomes passive in nitric acid of sufficient concentration. Access through your institution Buy or subscribe This is a preview


of subscription content, access via your institution ACCESS OPTIONS Access through your institution Subscribe to this journal Receive 51 print issues and online access $199.00 per year only


$3.90 per issue Learn more Buy this article * Purchase on SpringerLink * Instant access to full article PDF Buy now Prices may be subject to local taxes which are calculated during checkout


ADDITIONAL ACCESS OPTIONS: * Log in * Learn about institutional subscriptions * Read our FAQs * Contact customer support SIMILAR CONTENT BEING VIEWED BY OTHERS CORROSION INHIBITION OF COPPER


IN FERRIC CHLORIDE SOLUTIONS WITH ORGANIC INHIBITORS Article Open access 18 November 2020 CHEMICAL, ELECTROCHEMICAL, AND QUANTUM INVESTIGATION INTO THE USE OF AN ORGANOPHOSPHORUS DERIVATIVE


TO INHIBIT COPPER CORROSION IN ACIDIC ENVIRONMENTS Article Open access 18 May 2024 MICROBIALLY MEDIATED METAL CORROSION Article 21 June 2023 AUTHOR INFORMATION AUTHORS AND AFFILIATIONS *


Bedford Modern School, W. HUGHES Authors * W. HUGHES View author publications You can also search for this author inPubMed Google Scholar RIGHTS AND PERMISSIONS Reprints and permissions


ABOUT THIS ARTICLE CITE THIS ARTICLE HUGHES, W. The Passivity of Metals. _Nature_ 106, 692–693 (1921). https://doi.org/10.1038/106692c0 Download citation * Published: 01 January 1921 * Issue


Date: 27 January 1921 * DOI: https://doi.org/10.1038/106692c0 SHARE THIS ARTICLE Anyone you share the following link with will be able to read this content: Get shareable link Sorry, a


shareable link is not currently available for this article. Copy to clipboard Provided by the Springer Nature SharedIt content-sharing initiative