A method for determining the ratio of the michael is constants of an enzyme with respect to two substrates

A method for determining the ratio of the michael is constants of an enzyme with respect to two substrates

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ABSTRACT THE extension of the Michaelis–Menten theory to a mixture of two substrates and an enzyme which attacks both given by Thorn1 has also been worked out by us and appears in a publication now in the press2. We have given a method of obtaining the ratio of the Michaelis constants which is simpler than his. Using Thorn's symbols, his last equation but one simplifies to where V_m_ is the maximum initial velocity of the mixed substrates. This equation can be transformed into, the equation Access through your institution Buy or subscribe This is a preview of subscription content, access via your institution ACCESS OPTIONS Access through your institution Subscribe to this journal Receive 51 print issues and online access $199.00 per year only $3.90 per issue Learn more Buy this article * Purchase on SpringerLink * Instant access to full article PDF Buy now Prices may be subject to local taxes which are calculated during checkout ADDITIONAL ACCESS OPTIONS: * Log in * Learn about institutional subscriptions * Read our FAQs * Contact customer support SIMILAR CONTENT BEING VIEWED BY OTHERS THE MEASUREMENT OF TRUE INITIAL RATES IS NOT ALWAYS ABSOLUTELY NECESSARY TO ESTIMATE ENZYME KINETIC PARAMETERS Article Open access 12 September 2023 HIGH-ORDER MICHAELIS-MENTEN EQUATIONS ALLOW INFERENCE OF HIDDEN KINETIC PARAMETERS IN ENZYME CATALYSIS Article Open access 20 March 2025 SINGLE TIME-POINT ANALYSIS OF PRODUCT AND SUBSTRATE INHIBITION Article Open access 05 October 2024 REFERENCES * Thorn, M. B., _Nature_, 164, 27 (1949). Article  ADS  CAS  Google Scholar  * Adams, D. H., and Whittaker, V. P., _Biochim. et Biophys. Acta_ (in the press). Download references AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Department of Biochemistry, University of Oxford. London Hospital, London, E.1 V. P. WHITTAKER & D. H. ADAMS Authors * V. P. WHITTAKER View author publications You can also search for this author inPubMed Google Scholar * D. H. ADAMS View author publications You can also search for this author inPubMed Google Scholar RIGHTS AND PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE WHITTAKER, V., ADAMS, D. A Method for Determining the Ratio of the Michael is Constants of an Enzyme with Respect to Two Substrates. _Nature_ 164, 315–316 (1949). https://doi.org/10.1038/164315a0 Download citation * Issue Date: 20 August 1949 * DOI: https://doi.org/10.1038/164315a0 SHARE THIS ARTICLE Anyone you share the following link with will be able to read this content: Get shareable link Sorry, a shareable link is not currently available for this article. Copy to clipboard Provided by the Springer Nature SharedIt content-sharing initiative

ABSTRACT THE extension of the Michaelis–Menten theory to a mixture of two substrates and an enzyme which attacks both given by Thorn1 has also been worked out by us and appears in a


publication now in the press2. We have given a method of obtaining the ratio of the Michaelis constants which is simpler than his. Using Thorn's symbols, his last equation but one


simplifies to where V_m_ is the maximum initial velocity of the mixed substrates. This equation can be transformed into, the equation Access through your institution Buy or subscribe This is


a preview of subscription content, access via your institution ACCESS OPTIONS Access through your institution Subscribe to this journal Receive 51 print issues and online access $199.00 per


year only $3.90 per issue Learn more Buy this article * Purchase on SpringerLink * Instant access to full article PDF Buy now Prices may be subject to local taxes which are calculated


during checkout ADDITIONAL ACCESS OPTIONS: * Log in * Learn about institutional subscriptions * Read our FAQs * Contact customer support SIMILAR CONTENT BEING VIEWED BY OTHERS THE


MEASUREMENT OF TRUE INITIAL RATES IS NOT ALWAYS ABSOLUTELY NECESSARY TO ESTIMATE ENZYME KINETIC PARAMETERS Article Open access 12 September 2023 HIGH-ORDER MICHAELIS-MENTEN EQUATIONS ALLOW


INFERENCE OF HIDDEN KINETIC PARAMETERS IN ENZYME CATALYSIS Article Open access 20 March 2025 SINGLE TIME-POINT ANALYSIS OF PRODUCT AND SUBSTRATE INHIBITION Article Open access 05 October


2024 REFERENCES * Thorn, M. B., _Nature_, 164, 27 (1949). Article  ADS  CAS  Google Scholar  * Adams, D. H., and Whittaker, V. P., _Biochim. et Biophys. Acta_ (in the press). Download


references AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Department of Biochemistry, University of Oxford. London Hospital, London, E.1 V. P. WHITTAKER & D. H. ADAMS Authors * V. P.


WHITTAKER View author publications You can also search for this author inPubMed Google Scholar * D. H. ADAMS View author publications You can also search for this author inPubMed Google


Scholar RIGHTS AND PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE WHITTAKER, V., ADAMS, D. A Method for Determining the Ratio of the Michael is Constants of an


Enzyme with Respect to Two Substrates. _Nature_ 164, 315–316 (1949). https://doi.org/10.1038/164315a0 Download citation * Issue Date: 20 August 1949 * DOI: https://doi.org/10.1038/164315a0


SHARE THIS ARTICLE Anyone you share the following link with will be able to read this content: Get shareable link Sorry, a shareable link is not currently available for this article. Copy to


clipboard Provided by the Springer Nature SharedIt content-sharing initiative