Clathrate hydrates of soluble non-electrolytes

Clathrate hydrates of soluble non-electrolytes

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ABSTRACT A NEW thermodynamic method1 for calculation of hydrate formulæ from aqueous solution freezing curves has revealed a number of non-electrolyte hydrates of unexpected formulæ which are probably characteristic of new groups of clathrate hydrates. In Table 1, data are presented for these hydrates showing the calculated hydrate formula with its 95 per cent confidence limit of error, the structurally probable water : hydrate-former combining ratio number _n_, the congruent freezing point (° C) and reference to the original freezing point measurements. Access through your institution Buy or subscribe This is a preview of subscription content, access via your institution ACCESS OPTIONS Access through your institution Subscribe to this journal Receive 51 print issues and online access $199.00 per year only $3.90 per issue Learn more Buy this article * Purchase on SpringerLink * Instant access to full article PDF Buy now Prices may be subject to local taxes which are calculated during checkout ADDITIONAL ACCESS OPTIONS: * Log in * Learn about institutional subscriptions * Read our FAQs * Contact customer support SIMILAR CONTENT BEING VIEWED BY OTHERS UNRAVELING THE PHASE DIAGRAM-ION TRANSPORT RELATIONSHIP IN AQUEOUS ELECTROLYTE SOLUTIONS AND CORRELATING CONDUCTIVITY WITH CONCENTRATION AND TEMPERATURE BY SEMI-EMPIRICAL MODELING Article Open access 12 September 2023 A THERMODYNAMIC FRAMEWORK TO IDENTIFY APPOSITE REFRIGERANT FORMER FOR HYDRATE-BASED APPLICATIONS Article Open access 06 October 2022 INVESTIGATING THE PHASE DIAGRAM-IONIC CONDUCTIVITY ISOTHERM RELATIONSHIP IN AQUEOUS SOLUTIONS OF COMMON ACIDS: HYDROCHLORIC, NITRIC, SULFURIC AND PHOSPHORIC ACID Article Open access 03 April 2024 REFERENCES * Glew, D. N., Symp. Thermodynamics and Thermochemistry, Intern. Union Pure and App. Chem., Lund, Sweden, July 1963. * Pickering, S. U., _Trans. Chem. Soc._, 63, I, 141 (1893). Article  CAS  Google Scholar  * Somerville, W. C., _J. Phys. Chem._, 35, 2412 (1931). Article  CAS  Google Scholar  * Maass, O., and Boomer, E. H., _J. Amer. Chem. Soc._, 43, 1709 (1922). Article  Google Scholar  * Pauling, L., and Marsh, R. E., _Proc. U.S. Nat. Acad. Sci._, 38, 112 (1952). von Stackelberg, M., and Müller, H. R., _Z. Electrochem._, 58, 25 (1954). Article  ADS  CAS  Google Scholar  * Feil, D., and Jeffrey, G. A., _J. Chem. Phys._, 35, 1863 (1961). Article  ADS  CAS  Google Scholar  * Von Stackelberg, M., and Meuthen, B., _Z. Elektrochem._, 62, 130 (1958). Google Scholar  * Jeffrey, G. A., and McMullan, R. K., _J. Chem. Phys._, 37, 2231 (1962). Article  ADS  CAS  Google Scholar  Download references AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Exploratory Research Laboratory, Dow Chemical of Canada, Ltd., Sarnia, Ontario D. N. GLEW Authors * D. N. GLEW View author publications You can also search for this author inPubMed Google Scholar RIGHTS AND PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE GLEW, D. Clathrate Hydrates of Soluble Non-electrolytes. _Nature_ 201, 922–923 (1964). https://doi.org/10.1038/201922b0 Download citation * Issue Date: 29 February 1964 * DOI: https://doi.org/10.1038/201922b0 SHARE THIS ARTICLE Anyone you share the following link with will be able to read this content: Get shareable link Sorry, a shareable link is not currently available for this article. Copy to clipboard Provided by the Springer Nature SharedIt content-sharing initiative

ABSTRACT A NEW thermodynamic method1 for calculation of hydrate formulæ from aqueous solution freezing curves has revealed a number of non-electrolyte hydrates of unexpected formulæ which


are probably characteristic of new groups of clathrate hydrates. In Table 1, data are presented for these hydrates showing the calculated hydrate formula with its 95 per cent confidence


limit of error, the structurally probable water : hydrate-former combining ratio number _n_, the congruent freezing point (° C) and reference to the original freezing point measurements.


Access through your institution Buy or subscribe This is a preview of subscription content, access via your institution ACCESS OPTIONS Access through your institution Subscribe to this


journal Receive 51 print issues and online access $199.00 per year only $3.90 per issue Learn more Buy this article * Purchase on SpringerLink * Instant access to full article PDF Buy now


Prices may be subject to local taxes which are calculated during checkout ADDITIONAL ACCESS OPTIONS: * Log in * Learn about institutional subscriptions * Read our FAQs * Contact customer


support SIMILAR CONTENT BEING VIEWED BY OTHERS UNRAVELING THE PHASE DIAGRAM-ION TRANSPORT RELATIONSHIP IN AQUEOUS ELECTROLYTE SOLUTIONS AND CORRELATING CONDUCTIVITY WITH CONCENTRATION AND


TEMPERATURE BY SEMI-EMPIRICAL MODELING Article Open access 12 September 2023 A THERMODYNAMIC FRAMEWORK TO IDENTIFY APPOSITE REFRIGERANT FORMER FOR HYDRATE-BASED APPLICATIONS Article Open


access 06 October 2022 INVESTIGATING THE PHASE DIAGRAM-IONIC CONDUCTIVITY ISOTHERM RELATIONSHIP IN AQUEOUS SOLUTIONS OF COMMON ACIDS: HYDROCHLORIC, NITRIC, SULFURIC AND PHOSPHORIC ACID


Article Open access 03 April 2024 REFERENCES * Glew, D. N., Symp. Thermodynamics and Thermochemistry, Intern. Union Pure and App. Chem., Lund, Sweden, July 1963. * Pickering, S. U., _Trans.


Chem. Soc._, 63, I, 141 (1893). Article  CAS  Google Scholar  * Somerville, W. C., _J. Phys. Chem._, 35, 2412 (1931). Article  CAS  Google Scholar  * Maass, O., and Boomer, E. H., _J. Amer.


Chem. Soc._, 43, 1709 (1922). Article  Google Scholar  * Pauling, L., and Marsh, R. E., _Proc. U.S. Nat. Acad. Sci._, 38, 112 (1952). von Stackelberg, M., and Müller, H. R., _Z.


Electrochem._, 58, 25 (1954). Article  ADS  CAS  Google Scholar  * Feil, D., and Jeffrey, G. A., _J. Chem. Phys._, 35, 1863 (1961). Article  ADS  CAS  Google Scholar  * Von Stackelberg, M.,


and Meuthen, B., _Z. Elektrochem._, 62, 130 (1958). Google Scholar  * Jeffrey, G. A., and McMullan, R. K., _J. Chem. Phys._, 37, 2231 (1962). Article  ADS  CAS  Google Scholar  Download


references AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Exploratory Research Laboratory, Dow Chemical of Canada, Ltd., Sarnia, Ontario D. N. GLEW Authors * D. N. GLEW View author


publications You can also search for this author inPubMed Google Scholar RIGHTS AND PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE GLEW, D. Clathrate Hydrates of


Soluble Non-electrolytes. _Nature_ 201, 922–923 (1964). https://doi.org/10.1038/201922b0 Download citation * Issue Date: 29 February 1964 * DOI: https://doi.org/10.1038/201922b0 SHARE THIS


ARTICLE Anyone you share the following link with will be able to read this content: Get shareable link Sorry, a shareable link is not currently available for this article. Copy to clipboard


Provided by the Springer Nature SharedIt content-sharing initiative