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ABSTRACT We investigated the effect of interfacial reaction and morphology on the rheological properties of a reactive bilayer polymer system consisting of end-functionalized polystyrene
with carboxylic acid (PS-mCOOH) and poly(methyl methacrylate-_ran_-glycidylmethacrylate) (PMMA-GMA). We found that the complex viscosity (|η*|) of the reactive bilayer was unusually higher
than the predicted value from the inverse relationship which holds for non-reactive bilayer, even though the interfacial roughness generated from PMMA-_graft_-PS copolymers formed _in situ_
from the reaction near the interface was much smaller than the thicknesses of two plates of PS-mCOOH and PMMA-GMA. This indicates that in addition to the effect of the improved mechanical
strength or interfacial mixing between chains by the presence of graft copolymers located near the interface, the roughness of the interface greatly influences |η*| of the reactive bilayer.
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REFERENCES * D. R. Paul and S. Newman, “Polymer Blends,” Academic Press, New York, 1978, VOL. 1. * L. A. Utracki, “Polymer Alloys and Blends,” Hanser, New York, w Yor. * C. D. Han and T. C.
Yu, _J. Appl. Polym. Sci._, 15, 1163 (1971). * L. A. Utracki and M. R. Kamal, _Polym. Eng. Sci._, 22, 96 (1982). * N. Alle and J. Lyngaae-Jorgensen, _Rheol. Acta_, 19, 94 (1980). * Y. C.
Kim, S. J. Lee, J. C. Kim, and H. Cho, _Polym. J._, 37, 206 (2005). * C. D. Han and T. C. Yu, _Polym. Eng. Sci._, 12, 81 (1972). * C. K. Shih, _Polym. Eng. Sci._, 16, 742 (1976). * S. Danesi
and S. R. Porter, _Polymer_, 19, 448 (1978). * Y. S. Lipatov, V. F. Shumsky, A. N. Gorbatenko, Y. N. Panov, and L. S. Bolotnikova, _J. Appl. Polym. Sci._, 26, 499 (1981). * C. D. Han and H.
H. Yang, _J. Appl. Polym. Sci._, 33, 1199 (1987). * C. D. Han and H. H. Yang, _J. Appl. Polym. Sci._, 33, 1221 (1987). * C. D. Han and J. K. Kim, _Macromolecules_, 22, 1914 (1989). * C. D.
Han and J. K. Kim, _Macromolecules_, 22, 4292 (1989). * C. D. Han, H. S. Chung, and J. K. Kim, _Polymer_, 33, 546 (1992). * J. K. Kim, C. D. Han, and Y. J. Lee, _Polym. J._, 24, 205 (1992).
* C. D. Han, “Multiphase Flow in Polymer Processing,” Academic Press, New York, 1981. * N. Grizzuti, G. Buonocore, and G. Iorioc, _J. Rheol._, 44, 149 (2000). * L. A. Utracki, “Commercial
Polymer Blends,” Chapman&Hall, New York, 1998. * I. K. Andrea, A. P. Anastasia, TH. G. Stella, M. Marie-Claude, V.-M. Claire, and V. N. Anastasios, _Electroanalysis_, 18, 456 (2006). *
W. M. Diffey, R. H. Trimm, M. G. Temmen, and P. R. Ashley, _J. Lightwave Technol._, 23, 1787 (2005). * K. Lamnawar and A. Maazouz, _Rheol. Acta_, 45, 411 (2006). * R. F. Heitmiller, R. Z.
Naar, and H. H. Zabusky, _J. Appl. Polym. Sci._, 8, 873 (1964). * J. Zhao, L. Mascia, and V. Nassehi, _Adv. Polym. Technol._, 16, 209 (1997). * R. Zhao and C. W. Macosko, _J. Rheol._, 46,
145 (2002). * H. Y. Kim, U. Jeong, and J. K. Kim, _Macromolecules_, 36, 1594 (2003). * X. Yu, Y. Wu, B. Li, and Y. Han, _Polymer_, 46, 3337 (2005). * J. K. Kim and H. Lee, _Polymer_, 37, 305
(1996). * H. K. Jeon and J. K. Kim, _Macromolecules_, 31, 9273 (1998). * H. K. Jeon and J. K. Kim, _Polymer_, 39, 6227 (1998). * H. K. Jeon and J. K. Kim, _Korea. Polym. J._, 7, 124 (1999).
* K. K. Jeon, H. T. O, and J. K. Kim, _Polymer_, 42, 3259 (2001). * H. K. Jeon and J. K. Kim, _Macromolecules_, 33, 8200 (2000). * H. Y. Kim, D. Y. Ryu, U. Jeong, D. H. Kho, and J. K. Kim,
_Macromol. Rapid Commun._, 26, 1428 (2005). * D. H. Kho, S. H. Chae, U. Jeong, H. Y. Kim, and J. K. Kim, _Macromolecules_, 38, 3820 (2005). * H. Y. Kim, D. H. Lee, and J. K. Kim, _Polymer_,
47, 5108 (2006). * S. Y. Yang, I. Ryu, H. Y. Kim, J. K. Kim, S. K. Jang, and T. P. Russell, _Adv. Mater._, 18, 709 (2006). * U. Jeong, D. Y. Ryu, J. K. Kim, D. H. Kim, T. P. Russell, and C.
J. Hawker, _Adv. Mater._, 15, 1247 (2003). * D. Graebling, R. Muller, and J. F. Palierne, _Macromolecules_, 26, 320 (1993). * J. F. Palierne, _Rheol. Acta_, 29, 204 (1990). Download
references AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Department of Chemical Engineering and Polymer Research Institute, National Creative Research Center for Block Copolymer
Self-Assembly, Pohang University of Science & Technology, Kyungbuk, 790-784, Korea Hwang Yong Kim, Hye Jeong Kim & Jin Kon Kim Authors * Hwang Yong Kim View author publications You
can also search for this author inPubMed Google Scholar * Hye Jeong Kim View author publications You can also search for this author inPubMed Google Scholar * Jin Kon Kim View author
publications You can also search for this author inPubMed Google Scholar CORRESPONDING AUTHOR Correspondence to Jin Kon Kim. RIGHTS AND PERMISSIONS Reprints and permissions ABOUT THIS
ARTICLE CITE THIS ARTICLE Kim, H., Kim, H. & Kim, J. Effect of Interfacial Reaction and Morphology on Rheological Properties of Reactive Bilayer. _Polym J_ 38, 1165–1172 (2006).
https://doi.org/10.1295/polymj.PJ2006086 Download citation * Received: 31 July 2006 * Accepted: 25 August 2006 * Published: 11 October 2006 * Issue Date: 01 November 2006 * DOI:
https://doi.org/10.1295/polymj.PJ2006086 SHARE THIS ARTICLE Anyone you share the following link with will be able to read this content: Get shareable link Sorry, a shareable link is not
currently available for this article. Copy to clipboard Provided by the Springer Nature SharedIt content-sharing initiative KEYWORDS * Rheological Properties * Reactive Polymer Bilayer *
Interfacial Roughness