Hydrolytic co-condensation of phenyltriethoxysilane with γ-aminopropyltriethoxysilane in the presence of sodium dodecyl sulfate

Hydrolytic co-condensation of phenyltriethoxysilane with γ-aminopropyltriethoxysilane in the presence of sodium dodecyl sulfate

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ABSTRACT The hydrolytic co-condensation of hydrophobic phenyltriethoxysilane (PTES) and hydrophilic γ-aminopropyltriethoxysilane (APS) under basic catalysis in the presence of sodium dodecyl sulfate (SDS) was investigated. Copolymer particles were influenced significantly by APS/PTES molar ratios, total monomer and SDS concentration. Amino group content of the copolymer was determined by element analysis and back titration. Scanning electron micrographs revealed the morphologies of the copolymer particles. FT-IR, solid state 29Si NMR and TGA were used to characterize the copolymer. SIMILAR CONTENT BEING VIEWED BY OTHERS EFFECT OF ADDING LITHIUM CHLORIDE ON THE RADICAL COPOLYMERIZATION OF LITHIUM _P_-STYRENESULFONATE AND ACRYLAMIDE Article 19 June 2023 CHEMOSELECTIVE TRANSESTERIFICATION AND POLYMER SYNTHESIS USING A ZINCATE COMPLEX Article 18 September 2020 ANIONIC RING-OPENING POLYMERIZATION OF FUNCTIONAL EPOXIDE MONOMERS IN THE SOLID STATE Article Open access 20 September 2023 ARTICLE PDF REFERENCES * R. H. Baney, M. Itoh, A. Sakakibara, and T. Suzuki, _Chem. Rev._, 95, 1409 (1995). * K. M. Kim, T. Ogoshi, and Y. Chujo, _J. Polym. Sci., Part A: Polym. Chem._, 43, 473 (2005). * M. C. Gravel, C. Zhang, M. Dinderman, and R. M. Laine, _Appl. Organomet. Chem._, 13, 329 (1999). * Y. Kaneko, N. Iyi, T. Matsumoto, K. Fujii, K. Kurashima, and T. Fujita, _J. Mater. Chem._, 13, 2058 (2003). * F. J. Feher and K. D. Wyndham, _Chem. Commun._, 3, 323 (1998). * D. R. Bujalski, H. P. Chen, G. A. Zank, and K. Suo, _Macromolecules_, 36, 3529 (2003). * A. Matsuda, T. Tanaka, K. Tadanaga, T. Minami, and M. Tatsumisago, _J. Mater. Sci._, 39, 903 (2004). * S. E. Tunney, G. A. Rakes, and B. K. Coltrain, U.S. Patent 5 384 376 (1995). * S. E. Tunney, G. A. Rakes, and B. K. Coltrain, _Chem. Abstr._ 123, P145607w (1995). * S. M. Liu, X. M. Lang, H. Ye, S. J. Zhang, and J. Q. Zhao, _Eur. Polym. J._, 41, 996 (2005). * C. Ma and Y. Kimura, _Polym. J._, 34, 709 (2002). * C. Ma, I. Taniguchi, M. Miyamoto, and Y. Kimura, _Polym. J._, 35, 270 (2003). * N. Tsubokawa, T. Iida, and T. Takayama, _J. Appl. Polym. Sci._, 75, 515 (2000). * R. M. Ottenbrite, J. S. Wall, and J. A. Siddiqui, _J. Am. Ceram. Soc._, 83, 3214 (2000). Download references AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * College of Materials Science and Engineering, South China University of Technology, Guangzhou, 510640, China Shumei Liu, Hua Ye, Yongsheng Zhou & Jianqing Zhao * The Key Laboratory of GD for High Property and Functional Macromolecular Materials, South China University of Technology, Guangzhou, 510640, China Hua Ye & Jianqing Zhao Authors * Shumei Liu View author publications You can also search for this author inPubMed Google Scholar * Hua Ye View author publications You can also search for this author inPubMed Google Scholar * Yongsheng Zhou View author publications You can also search for this author inPubMed Google Scholar * Jianqing Zhao View author publications You can also search for this author inPubMed Google Scholar CORRESPONDING AUTHOR Correspondence to Jianqing Zhao. RIGHTS AND PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE Liu, S., Ye, H., Zhou, Y. _et al._ Hydrolytic Co-condensation of Phenyltriethoxysilane with γ-Aminopropyltriethoxysilane in the Presence of Sodium Dodecyl Sulfate. _Polym J_ 38, 220–225 (2006). https://doi.org/10.1295/polymj.38.220 Download citation * Received: 05 August 2005 * Accepted: 04 October 2005 * Published: 15 February 2006 * Issue Date: 01 March 2006 * DOI: https://doi.org/10.1295/polymj.38.220 SHARE THIS ARTICLE Anyone you share the following link with will be able to read this content: Get shareable link Sorry, a shareable link is not currently available for this article. Copy to clipboard Provided by the Springer Nature SharedIt content-sharing initiative KEYWORDS * γ-Aminopropyltriethoxysilane * Phenyltriethoxysilane * Sodium Dodecyl Sulfate * Hydrolytic Co-condensation * Copolymer Particles

ABSTRACT The hydrolytic co-condensation of hydrophobic phenyltriethoxysilane (PTES) and hydrophilic γ-aminopropyltriethoxysilane (APS) under basic catalysis in the presence of sodium dodecyl


sulfate (SDS) was investigated. Copolymer particles were influenced significantly by APS/PTES molar ratios, total monomer and SDS concentration. Amino group content of the copolymer was


determined by element analysis and back titration. Scanning electron micrographs revealed the morphologies of the copolymer particles. FT-IR, solid state 29Si NMR and TGA were used to


characterize the copolymer. SIMILAR CONTENT BEING VIEWED BY OTHERS EFFECT OF ADDING LITHIUM CHLORIDE ON THE RADICAL COPOLYMERIZATION OF LITHIUM _P_-STYRENESULFONATE AND ACRYLAMIDE Article 19


June 2023 CHEMOSELECTIVE TRANSESTERIFICATION AND POLYMER SYNTHESIS USING A ZINCATE COMPLEX Article 18 September 2020 ANIONIC RING-OPENING POLYMERIZATION OF FUNCTIONAL EPOXIDE MONOMERS IN


THE SOLID STATE Article Open access 20 September 2023 ARTICLE PDF REFERENCES * R. H. Baney, M. Itoh, A. Sakakibara, and T. Suzuki, _Chem. Rev._, 95, 1409 (1995). * K. M. Kim, T. Ogoshi, and


Y. Chujo, _J. Polym. Sci., Part A: Polym. Chem._, 43, 473 (2005). * M. C. Gravel, C. Zhang, M. Dinderman, and R. M. Laine, _Appl. Organomet. Chem._, 13, 329 (1999). * Y. Kaneko, N. Iyi, T.


Matsumoto, K. Fujii, K. Kurashima, and T. Fujita, _J. Mater. Chem._, 13, 2058 (2003). * F. J. Feher and K. D. Wyndham, _Chem. Commun._, 3, 323 (1998). * D. R. Bujalski, H. P. Chen, G. A.


Zank, and K. Suo, _Macromolecules_, 36, 3529 (2003). * A. Matsuda, T. Tanaka, K. Tadanaga, T. Minami, and M. Tatsumisago, _J. Mater. Sci._, 39, 903 (2004). * S. E. Tunney, G. A. Rakes, and


B. K. Coltrain, U.S. Patent 5 384 376 (1995). * S. E. Tunney, G. A. Rakes, and B. K. Coltrain, _Chem. Abstr._ 123, P145607w (1995). * S. M. Liu, X. M. Lang, H. Ye, S. J. Zhang, and J. Q.


Zhao, _Eur. Polym. J._, 41, 996 (2005). * C. Ma and Y. Kimura, _Polym. J._, 34, 709 (2002). * C. Ma, I. Taniguchi, M. Miyamoto, and Y. Kimura, _Polym. J._, 35, 270 (2003). * N. Tsubokawa, T.


Iida, and T. Takayama, _J. Appl. Polym. Sci._, 75, 515 (2000). * R. M. Ottenbrite, J. S. Wall, and J. A. Siddiqui, _J. Am. Ceram. Soc._, 83, 3214 (2000). Download references AUTHOR


INFORMATION AUTHORS AND AFFILIATIONS * College of Materials Science and Engineering, South China University of Technology, Guangzhou, 510640, China Shumei Liu, Hua Ye, Yongsheng Zhou & 


Jianqing Zhao * The Key Laboratory of GD for High Property and Functional Macromolecular Materials, South China University of Technology, Guangzhou, 510640, China Hua Ye & Jianqing Zhao


Authors * Shumei Liu View author publications You can also search for this author inPubMed Google Scholar * Hua Ye View author publications You can also search for this author inPubMed 


Google Scholar * Yongsheng Zhou View author publications You can also search for this author inPubMed Google Scholar * Jianqing Zhao View author publications You can also search for this


author inPubMed Google Scholar CORRESPONDING AUTHOR Correspondence to Jianqing Zhao. RIGHTS AND PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE Liu, S., Ye, H.,


Zhou, Y. _et al._ Hydrolytic Co-condensation of Phenyltriethoxysilane with γ-Aminopropyltriethoxysilane in the Presence of Sodium Dodecyl Sulfate. _Polym J_ 38, 220–225 (2006).


https://doi.org/10.1295/polymj.38.220 Download citation * Received: 05 August 2005 * Accepted: 04 October 2005 * Published: 15 February 2006 * Issue Date: 01 March 2006 * DOI:


https://doi.org/10.1295/polymj.38.220 SHARE THIS ARTICLE Anyone you share the following link with will be able to read this content: Get shareable link Sorry, a shareable link is not


currently available for this article. Copy to clipboard Provided by the Springer Nature SharedIt content-sharing initiative KEYWORDS * γ-Aminopropyltriethoxysilane * Phenyltriethoxysilane *


Sodium Dodecyl Sulfate * Hydrolytic Co-condensation * Copolymer Particles