Amylose selectively includes a specific range of molecular weights in poly(tetrahydrofuran)s in vine-twining polymerization

Amylose selectively includes a specific range of molecular weights in poly(tetrahydrofuran)s in vine-twining polymerization

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ARTICLE PDF REFERENCES * C. J. Pedersen, _J. Am. Chem. Soc._, 89, 7017 (1967). * G. W. Gokel, W. M. Leevy, and M. E. Weber, _Chem. Rev._, 104, 2723 (2004). * A. Harada, M. Okada, J. Li, and M. Kamachi, _Macromolecules_, 28, 8406 (1995). * M. Kowblansky, _Macromolecules_, 18, 1776 (1985). * O. K. Kim, L. S. Choi, H. Y. Zhang, X. H. He, and Y. H. Shih, _J. Am. Chem. Soc._, 118, 12220 (1996). * L. S. Choi and O. K. Kim, _Macromolecules_, 31, 9406 (1998). * T. Sanji, N. Kato, M. Kato, and M. Tanaka, _Angew. Chem., Int. Ed._, 44, 7301 (2005). * I. Lalush, H. Bar, I. Zakaria, S. Eichler, and E. Shimoni, _Biomacromolecules_, 6, 121 (2005). * T. Sanji, N. Kato, and M. Tanaka, _Macromolecules_, 39, 7508 (2006). * O. K. Kim, J. Je, and J. S. Melinger, _J. Am. Chem. Soc._, 128, 4532 (2006). * T. Sanji, N. Kato, and M. Tanaka, _Org. Lett._, 8, 235 (2006). * R. L. Shogren, R. V. Green, and Y. V. Wu, _J. Appl. Polym. Sci._, 42, 1701 (1991). * R. L. Shogren, _Carbohydr. Polym._, 22, 93 (1993). * A. Star, D. W. Steuerman, J. R. Heath, and J. F. Stoddart, _Angew. Chem., Int. Ed._, 41, 2508 (2002). * M. Ikeda, Y. Furusho, K. Okoshi, S. Tanahara, K. Maeda, S. Nishino, T. Mori, and E. Yashima, _Angew. Chem., Int. Ed._, 45, 6491 (2006). * T. Kida, T. Minabe, S. Okada, and M. Akashi, _Chem. Commun._, 1559 (2007). * M. J. Frampton, T. D. W. Claridge, G. Latini, S. Brovelli, F. Cacialli, and H. L. Anderson, _Chem. Commun._, 2797 (2008). * The enzymatic polymerization is a useful tool for the regio- and stereocontrolled preparation of polysaccharides: * S. Kobayashi, H. Uyama, and S. Kimura, _Chem. Rev._, 101, 3793 (2001). * S. Shoda, R. Izumi, and M. Fujita, _Bull. Chem. Soc. Jpn._, 76, 1 (2003). * S. Kobayashi, M. Ohmae, S. Fujikawa, and H. Ochiai, _Macromol. Symp._, 226, 147 (2005). * S. Kobayashi and M. Ohmae, _Adv. Polym. Sci._, 194, 159 (2006).For example, phosphorylase-catalyzed enzymatic polymerization using α-D-glucose 1-phosphate (G-1-P) proceeds with the regio-and stereoselective construction of an α-glycosidic bond under mild conditions, leading to the direct formation of amylose in aqueous media. This polymerization is initiated from a maltooligosaccharide primer such as G7. Then, the propagation proceeds through the following reversible reaction to produce a (l→4)-α-glucan chain, _i.e_., amylose: [(α, 1→4)-G]n + G-1-P ⇆ [(α, 1→4)-G]n+1 + P In the reaction, a glucose unit is transferred from G-1-P to the nonreducing 4-OH terminus of a (l→4)-α-glucan chain, resulting in inorganic phosphate (P): * G. Ziegast and B. Pfannemüller, _Carbohydr. Res._, 160, 185 (1987). * J. Kadokawa, Y. Kaneko, H. Tagaya, and K. Chiba, _Chem. Commun._, 449 (2001). * J. Kadokawa, Y. Kaneko, A. Nakaya, and H. Tagaya, _Macro-molecules_, 34, 6536 (2001). * J. Kadokawa, Y. Kaneko, S. Nagase, T. Takahashi, and H. Tagaya, _Chem. Eur. J._, 8, 3321 (2002). * J. Kadokawa, A. Nakaya, Y. Kaneko, and H. Tagaya, _Macromol. Chem. Phys._, 204, 1451 (2003). * Y. Kaneko and J. Kadokawa, _Chem. Rec._, 5, 36 (2005). * Y. Kaneko and J. Kadokawa, _J. Biomater. Sci., Polym. Ed._, 17, 1269 (2006). * Y. Kaneko, K. Beppu, and J. Kadokawa, _Biomacromolecules_, 8, 2983 (2007). * Y. Kaneko, K. Beppu, and J. Kadokawa, _Macromol. Chem. Phys._, 209, 1037 (2008). * Y. Kaneko, Y. Saito, A. Nakaya, J. Kadokawa, and H. Tagaya, _Macromolecules_, 41, 5665 (2008). * Y. Kaneko, K. Beppu, T. Kyutoku, and J. Kadokawa, _Polym. J._, 41, 279 (2009). * M. Yanase, H. Takata, K. Fujii, T. Takaha, and T. Kuriki, _Appl. Environ. Microbiol._, 71, 5433 (2005). * S. Smith and A. J. Hubin, _J. Macromol. Sci., Part A: Pure Appl. Chem._, 7, 1399 (1973). * V. V. Braunmühl, G. Jonas, and R. Stadler, _Macromolecules_, 28, 17 (1995). * H. D. Seneviratne and C. G. Biliaderis, _J. Cereal Sci._, 13, 129 (1991). * N. Jeannette, S. Bettina, C. F. Béatrice, and E. Felix, _Food Hydrocolloids_, 11, 27 (1997). Download references AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Graduate School of Science and Engineering, Kagoshima University, 1-21-40 Korimoto, Kagoshima, 890-0065, Japan Yoshiro Kaneko, Koutarou Beppu & Jun-ichi Kadokawa Authors * Yoshiro Kaneko View author publications You can also search for this author inPubMed Google Scholar * Koutarou Beppu View author publications You can also search for this author inPubMed Google Scholar * Jun-ichi Kadokawa View author publications You can also search for this author inPubMed Google Scholar CORRESPONDING AUTHOR Correspondence to Jun-ichi Kadokawa. RIGHTS AND PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE Kaneko, Y., Beppu, K. & Kadokawa, Ji. Amylose Selectively Includes a Specific Range of Molecular Weights in Poly(tetrahydrofuran)s in Vine-Twining Polymerization. _Polym J_ 41, 792–796 (2009). https://doi.org/10.1295/polymj.PJ2009104 Download citation * Received: 27 April 2009 * Accepted: 05 June 2009 * Published: 23 July 2009 * Issue Date: 01 September 2009 * DOI: https://doi.org/10.1295/polymj.PJ2009104 SHARE THIS ARTICLE Anyone you share the following link with will be able to read this content: Get shareable link Sorry, a shareable link is not currently available for this article. Copy to clipboard Provided by the Springer Nature SharedIt content-sharing initiative KEYWORDS * Amylose * Enzymatic Polymerization * Inclusion Complex * Poly(tetrahydrofuran) * Selective Inclusion * Vine-Twining Polymerization

ARTICLE PDF REFERENCES * C. J. Pedersen, _J. Am. Chem. Soc._, 89, 7017 (1967). * G. W. Gokel, W. M. Leevy, and M. E. Weber, _Chem. Rev._, 104, 2723 (2004). * A. Harada, M. Okada, J. Li, and


M. Kamachi, _Macromolecules_, 28, 8406 (1995). * M. Kowblansky, _Macromolecules_, 18, 1776 (1985). * O. K. Kim, L. S. Choi, H. Y. Zhang, X. H. He, and Y. H. Shih, _J. Am. Chem. Soc._, 118,


12220 (1996). * L. S. Choi and O. K. Kim, _Macromolecules_, 31, 9406 (1998). * T. Sanji, N. Kato, M. Kato, and M. Tanaka, _Angew. Chem., Int. Ed._, 44, 7301 (2005). * I. Lalush, H. Bar, I.


Zakaria, S. Eichler, and E. Shimoni, _Biomacromolecules_, 6, 121 (2005). * T. Sanji, N. Kato, and M. Tanaka, _Macromolecules_, 39, 7508 (2006). * O. K. Kim, J. Je, and J. S. Melinger, _J.


Am. Chem. Soc._, 128, 4532 (2006). * T. Sanji, N. Kato, and M. Tanaka, _Org. Lett._, 8, 235 (2006). * R. L. Shogren, R. V. Green, and Y. V. Wu, _J. Appl. Polym. Sci._, 42, 1701 (1991). * R.


L. Shogren, _Carbohydr. Polym._, 22, 93 (1993). * A. Star, D. W. Steuerman, J. R. Heath, and J. F. Stoddart, _Angew. Chem., Int. Ed._, 41, 2508 (2002). * M. Ikeda, Y. Furusho, K. Okoshi, S.


Tanahara, K. Maeda, S. Nishino, T. Mori, and E. Yashima, _Angew. Chem., Int. Ed._, 45, 6491 (2006). * T. Kida, T. Minabe, S. Okada, and M. Akashi, _Chem. Commun._, 1559 (2007). * M. J.


Frampton, T. D. W. Claridge, G. Latini, S. Brovelli, F. Cacialli, and H. L. Anderson, _Chem. Commun._, 2797 (2008). * The enzymatic polymerization is a useful tool for the regio- and


stereocontrolled preparation of polysaccharides: * S. Kobayashi, H. Uyama, and S. Kimura, _Chem. Rev._, 101, 3793 (2001). * S. Shoda, R. Izumi, and M. Fujita, _Bull. Chem. Soc. Jpn._, 76, 1


(2003). * S. Kobayashi, M. Ohmae, S. Fujikawa, and H. Ochiai, _Macromol. Symp._, 226, 147 (2005). * S. Kobayashi and M. Ohmae, _Adv. Polym. Sci._, 194, 159 (2006).For example,


phosphorylase-catalyzed enzymatic polymerization using α-D-glucose 1-phosphate (G-1-P) proceeds with the regio-and stereoselective construction of an α-glycosidic bond under mild conditions,


leading to the direct formation of amylose in aqueous media. This polymerization is initiated from a maltooligosaccharide primer such as G7. Then, the propagation proceeds through the


following reversible reaction to produce a (l→4)-α-glucan chain, _i.e_., amylose: [(α, 1→4)-G]n + G-1-P ⇆ [(α, 1→4)-G]n+1 + P In the reaction, a glucose unit is transferred from G-1-P to the


nonreducing 4-OH terminus of a (l→4)-α-glucan chain, resulting in inorganic phosphate (P): * G. Ziegast and B. Pfannemüller, _Carbohydr. Res._, 160, 185 (1987). * J. Kadokawa, Y. Kaneko, H.


Tagaya, and K. Chiba, _Chem. Commun._, 449 (2001). * J. Kadokawa, Y. Kaneko, A. Nakaya, and H. Tagaya, _Macro-molecules_, 34, 6536 (2001). * J. Kadokawa, Y. Kaneko, S. Nagase, T. Takahashi,


and H. Tagaya, _Chem. Eur. J._, 8, 3321 (2002). * J. Kadokawa, A. Nakaya, Y. Kaneko, and H. Tagaya, _Macromol. Chem. Phys._, 204, 1451 (2003). * Y. Kaneko and J. Kadokawa, _Chem. Rec._, 5,


36 (2005). * Y. Kaneko and J. Kadokawa, _J. Biomater. Sci., Polym. Ed._, 17, 1269 (2006). * Y. Kaneko, K. Beppu, and J. Kadokawa, _Biomacromolecules_, 8, 2983 (2007). * Y. Kaneko, K. Beppu,


and J. Kadokawa, _Macromol. Chem. Phys._, 209, 1037 (2008). * Y. Kaneko, Y. Saito, A. Nakaya, J. Kadokawa, and H. Tagaya, _Macromolecules_, 41, 5665 (2008). * Y. Kaneko, K. Beppu, T.


Kyutoku, and J. Kadokawa, _Polym. J._, 41, 279 (2009). * M. Yanase, H. Takata, K. Fujii, T. Takaha, and T. Kuriki, _Appl. Environ. Microbiol._, 71, 5433 (2005). * S. Smith and A. J. Hubin,


_J. Macromol. Sci., Part A: Pure Appl. Chem._, 7, 1399 (1973). * V. V. Braunmühl, G. Jonas, and R. Stadler, _Macromolecules_, 28, 17 (1995). * H. D. Seneviratne and C. G. Biliaderis, _J.


Cereal Sci._, 13, 129 (1991). * N. Jeannette, S. Bettina, C. F. Béatrice, and E. Felix, _Food Hydrocolloids_, 11, 27 (1997). Download references AUTHOR INFORMATION AUTHORS AND AFFILIATIONS *


Graduate School of Science and Engineering, Kagoshima University, 1-21-40 Korimoto, Kagoshima, 890-0065, Japan Yoshiro Kaneko, Koutarou Beppu & Jun-ichi Kadokawa Authors * Yoshiro


Kaneko View author publications You can also search for this author inPubMed Google Scholar * Koutarou Beppu View author publications You can also search for this author inPubMed Google


Scholar * Jun-ichi Kadokawa View author publications You can also search for this author inPubMed Google Scholar CORRESPONDING AUTHOR Correspondence to Jun-ichi Kadokawa. RIGHTS AND


PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE Kaneko, Y., Beppu, K. & Kadokawa, Ji. Amylose Selectively Includes a Specific Range of Molecular Weights in


Poly(tetrahydrofuran)s in Vine-Twining Polymerization. _Polym J_ 41, 792–796 (2009). https://doi.org/10.1295/polymj.PJ2009104 Download citation * Received: 27 April 2009 * Accepted: 05 June


2009 * Published: 23 July 2009 * Issue Date: 01 September 2009 * DOI: https://doi.org/10.1295/polymj.PJ2009104 SHARE THIS ARTICLE Anyone you share the following link with will be able to


read this content: Get shareable link Sorry, a shareable link is not currently available for this article. Copy to clipboard Provided by the Springer Nature SharedIt content-sharing


initiative KEYWORDS * Amylose * Enzymatic Polymerization * Inclusion Complex * Poly(tetrahydrofuran) * Selective Inclusion * Vine-Twining Polymerization