Play all audios:
The visible-light-driven thiolate-catalysed carboxylation of C(_sp_2)–H bonds in azines using CO2 is demonstrated. This procedure can be applied to various azine substrates to obtain a range
of N-heteroaromatic carboxylic acids with different functionalities, including bioactive molecules and carboxylated N-ligands. Access through your institution Buy or subscribe This is a
preview of subscription content, access via your institution ACCESS OPTIONS Access through your institution Subscribe to this journal Receive 12 digital issues and online access to articles
$119.00 per year only $9.92 per issue Learn more Buy this article * Purchase on SpringerLink * Instant access to full article PDF Buy now Prices may be subject to local taxes which are
calculated during checkout ADDITIONAL ACCESS OPTIONS: * Log in * Learn about institutional subscriptions * Read our FAQs * Contact customer support REFERENCES * Liu, Q., Wu, L., Jackstell,
R. & Beller, M. Using carbon dioxide as a building block in organic synthesis. _Nat. Commun._ 6, 5933 (2015). A REVIEW ARTICLE THAT PRESENTS THE APPLICATION OF CO2 IN ORGANIC SYNTHESIS.
Article ADS PubMed Google Scholar * Crisenza, G. E. M., Mazzarella, D. & Melchiorre, P. Synthetic methods driven by the photoactivity of electron donor–acceptor complexes. _J. Am.
Chem. Soc._ 142, 5461–5476 (2020). A REVIEW ARTICLE THAT PRESENTS THE APPLICATION OF EDA COMPLEXES IN ORGANIC SYNTHESIS. Article CAS PubMed PubMed Central Google Scholar * Wang, S.,
Wang, H. & König, B. Light-induced single-electron transfer processes involving sulfur anions as catalysts. _J. Am. Chem. Soc._ 143, 15530–15537 (2021). A REVIEW ARTICLE THAT PRESENTS
SULFUR ANIONS AS CATALYSTS IN PHOTOREDOX CATALYSIS. Article CAS PubMed Google Scholar * Ye, J.-H., Ju, T., Huang, H., Liao, L.-L. & Yu, D.-G. Radical carboxylative cyclizations and
carboxylations with CO2. _Acc. Chem. Res._ 54, 2518–2531 (2021). A REVIEW ARTICLE THAT PRESENTS VISIBLE-LIGHT-DRIVEN CARBOXYLATION USING CO2. Article CAS PubMed Google Scholar * Huang,
H. et al. Visible-light-driven anti-Markovnikov hydrocarboxylation of acrylates and styrenes with CO2. _CCS Chem._ 2, 1746–1756 (2020). THIS PAPER REPORTS THE VISIBLE-LIGHT-DRIVEN
THIOLATE-CATALYSED HYDROCARBOXYLATION OF ALKENES WITH CO2 VIA EDA COMPLEX FORMATION. Google Scholar * Miao, M. et al. Visible-light-driven thio-carboxylation of alkynes with CO2: facile
synthesis of thiochromones. _Sci. China Chem._ 66, 1457–1466 (2023). THIS PAPER REPORTS THE VISIBLE-LIGHT-DRIVEN THIO-CARBOXYLATION OF ALKYNES WITH CO2 VIA EDA COMPLEX FORMATION. Article
CAS Google Scholar Download references ADDITIONAL INFORMATION PUBLISHER’S NOTE Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional
affiliations. THIS IS A SUMMARY OF: Jiang, Y.-X. et al. Visible-light-driven synthesis of N-heteroaromatic carboxylic acids by thiolate-catalysed carboxylation of C(_sp_²)–H bonds using CO2.
_Nat. Synth_. https://doi.org/10.1038/s44160-023-00465-6 (2024). RIGHTS AND PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE A photocatalytic method for the
regioselective carboxylation of azine C–H bonds using CO2. _Nat. Synth_ 3, 305–306 (2024). https://doi.org/10.1038/s44160-023-00466-5 Download citation * Published: 12 January 2024 * Issue
Date: March 2024 * DOI: https://doi.org/10.1038/s44160-023-00466-5 SHARE THIS ARTICLE Anyone you share the following link with will be able to read this content: Get shareable link Sorry, a
shareable link is not currently available for this article. Copy to clipboard Provided by the Springer Nature SharedIt content-sharing initiative