Highly confined low-loss plasmons in graphene–boron nitride heterostructures

Highly confined low-loss plasmons in graphene–boron nitride heterostructures

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ABSTRACT Graphene plasmons were predicted to possess simultaneous ultrastrong field confinement and very low damping, enabling new classes of devices for deep-subwavelength metamaterials,


single-photon nonlinearities, extraordinarily strong light–matter interactions and nano-optoelectronic switches. Although all of these great prospects require low damping, thus far strong


plasmon damping has been observed, with both impurity scattering and many-body effects in graphene proposed as possible explanations. With the advent of van der Waals heterostructures, new


methods have been developed to integrate graphene with other atomically flat materials. In this Article we exploit near-field microscopy to image propagating plasmons in high-quality


graphene encapsulated between two films of hexagonal boron nitride (h-BN). We determine the dispersion and plasmon damping in real space. We find unprecedentedly low plasmon damping combined


with strong field confinement and confirm the high uniformity of this plasmonic medium. The main damping channels are attributed to intrinsic thermal phonons in the graphene and dielectric


losses in the h-BN. The observation and in-depth understanding of low plasmon damping is the key to the development of graphene nanophotonic and nano-optoelectronic devices. Access through


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CONTENT BEING VIEWED BY OTHERS TAILORED PLASMON POLARITON LANDSCAPE IN GRAPHENE/BORON NITRIDE PATTERNED HETEROSTRUCTURES Article Open access 24 May 2024 ANALYSIS OF PLASMON MODES IN


BI2SE3/GRAPHENE HETEROSTRUCTURES VIA ELECTRON ENERGY LOSS SPECTROSCOPY Article Open access 28 December 2024 OPTICAL ANISOTROPY IN VAN DER WAALS MATERIALS: IMPACT ON DIRECT EXCITATION OF


PLASMONS AND PHOTONS BY QUANTUM TUNNELING Article Open access 08 November 2021 REFERENCES * Dean, C. R. et al. Boron nitride substrates for high-quality graphene electronics. _Nature


Nanotech._ 5, 722–726 (2010). Article  CAS  Google Scholar  * Geim, A. K. & Grigorieva, I. V. Van der Waals heterostructures. _Nature_ 499, 419–425 (2013). Article  CAS  Google Scholar 


* Yankowitz, M. et al. Emergence of superlattice Dirac points in graphene on hexagonal boron nitride. _Nature Phys._ 8, 382–386 (2012). Article  CAS  Google Scholar  * Brar, V. W. et al.


Hybrid surface-phonon–plasmon polariton modes in graphene/monolayer h-BN heterostructures. _Nano Lett._ 14, 3876–3880 (2014). Article  CAS  Google Scholar  * Tomadin, A., Guinea, F. &


Polini, M. Generation and morphing of plasmons in graphene superlattices. _Phys. Rev. B_ 90, 161406(R) (2014). Article  Google Scholar  * Poddubny, A., Iorsh, I., Belov, P. & Kivshar, Y.


Hyperbolic metamaterials. _Nature Photon._ 7, 948–957 (2013). Article  CAS  Google Scholar  * Dai, S. et al. Tunable phonon polaritons in atomically thin van der Waals crystals of boron


nitride. _Science_ 343, 1125–1129 (2014). Article  CAS  Google Scholar  * Caldwell, J. D. et al. Sub-diffractional volume-confined polaritons in the natural hyperbolic material hexagonal


boron nitride. _Nature Commun._ 5, 5221 (2014). Article  CAS  Google Scholar  * Jablan, M., Buljan, H. & Soljačić, M. Plasmonics in graphene at infrared frequencies. _Phys. Rev. B_ 80,


245435 (2009). Article  Google Scholar  * Ju, L. et al. Graphene plasmonics for tunable terahertz metamaterials. _Nature Nanotech._ 6, 630–634 (2011). Article  CAS  Google Scholar  *


Nikitin, A. Y., Guinea, F., García-Vidal, F. J. & Martín-Moreno, L. Edge and waveguide terahertz surface plasmon modes in graphene microribbons. _Phys. Rev. B_ 84, 161407(R) (2011).


Article  Google Scholar  * Koppens, F. H. L., Chang, D. E. & García de Abajo, F. J. Graphene plasmonics: A platform for strong light-matter interactions. _Nano Lett._ 11, 3370–3377


(2011). Article  CAS  Google Scholar  * Grigorenko, A. N., Polini, M. & Novoselov, K. S. Graphene plasmonics. _Nature Photon._ 6, 749–758 (2012). CAS  Google Scholar  * Yan, H. et al.


Tunable infrared plasmonic devices using graphene/insulator stacks. _Nature Nanotech._ 7, 330–334 (2012). Article  CAS  Google Scholar  * Yan, H. et al. Damping pathways of mid-infrared


plasmons in graphene nanostructures. _Nature Photon._ 7, 394–399 (2013). Article  CAS  Google Scholar  * Brar, V. W., Jang, M. S., Sherrott, M., Lopez, J. J. & Atwater, H. A. Highly


confined tunable mid-infrared plasmonics in graphene nanoresonators. _Nano Lett._ 13, 2541–2547 (2013). Article  CAS  Google Scholar  * Jang, M. S. et al. Tunable large resonant absorption


in a midinfrared graphene Salisbury screen. _Phys. Rev. B_ 90, 165409 (2014). Article  Google Scholar  * Tassin, P., Koschny, T. & Soukoulis, C. M. Graphene for terahertz applications.


_Science_ 341, 620–621 (2013). Article  CAS  Google Scholar  * Low, T. & Avouris, P. Graphene plasmonics for terahertz to mid-infrared applications. _ACS Nano_ 8, 1086–1101 (2014).


Article  CAS  Google Scholar  * García de Abajo, F. J. Graphene plasmonics: Challenges and opportunities. _ACS Photonics_ 1, 135–152 (2014). Google Scholar  * Fang, Z. et al. Active tunable


absorption enhancement with graphene nanodisk arrays. _Nano Lett._ 14, 299–304 (2014). Article  CAS  Google Scholar  * Wang, L. et al. One-dimensional electrical contact to a two-dimensional


material. _Science_ 342, 614–617 (2013). Article  CAS  Google Scholar  * Fei, Z. et al. Gate-tuning of graphene plasmons revealed by infrared nano-imaging. _Nature_ 487, 82–85 (2012).


Article  CAS  Google Scholar  * Chen, J. et al. Optical nano-imaging of gate-tunable graphene plasmons. _Nature_ 487, 77–81 (2012). Article  CAS  Google Scholar  * Keilmann, F. &


Hillenbrand, R. Near-field microscopy by elastic light scattering from a tip. _Phil. Trans. R. Soc. Lond. A_ 362, 787–805 (2004). Article  CAS  Google Scholar  * Ocelic, N., Huber, A. &


Hillenbrand, R. Pseudoheterodyne detection for background-free near-field spectroscopy. _Appl. Phys. Lett._ 89, 101124 (2006). Article  Google Scholar  * Chen, J. et al. Strong plasmon


reflection at nanometer-size gaps in monolayer graphene on SiC. _Nano Lett._ 13, 6210–6215 (2013). Article  CAS  Google Scholar  * Fei, Z. et al. Electronic and plasmonic phenomena at


graphene grain boundaries. _Nature Nanotech._ 8, 821–825 (2013). Article  CAS  Google Scholar  * Schnell, M., Carney, P. S. & Hillenbrand, R. Synthetic optical holography for rapid


nanoimaging. _Nature Commun._ 5, 3499 (2014). Article  CAS  Google Scholar  * Alonso-González, P. et al. Controlling graphene plasmons with resonant metal antennas and spatial conductivity


patterns. _Science_ 344, 1369–1373 (2014). Article  Google Scholar  * Gerber, J. A., Berweger, S., O’Callahan, B. T. & Raschke, M. B. Phase-resolved surface pasmon interferometry of


graphene. _Phys. Rev. Lett._ 113, 055502 (2014). Article  Google Scholar  * Principi, A. et al. Plasmon losses due to electron–phonon scattering: The case of graphene encapsulated in


hexagonal boron nitride. _Phys. Rev. B_ 90, 165408 (2014). Article  Google Scholar  * Fei, Z. et al. Infrared nanoscopy of dirac plasmons at the graphene–SiO2 interface. _Nano Lett._ 11,


4701–4705 (2011). Article  CAS  Google Scholar  * Xue, J. et al. Scanning tunnelling microscopy and spectroscopy of ultra-flat graphene on hexagonal boron nitride. _Nature Mater._ 10,


282–285 (2011). Article  CAS  Google Scholar  * Zhang, L., Fu, X. & Yang, J. Excitation of propagating plasmons in semi-infinite graphene layer by free space photons. _Commun. Theory


Phys._ 61, 751–754 (2014). Article  CAS  Google Scholar  * Johnson, P. & Christy, R. Optical constants of the noble metals. _Phys. Rev. B_ 6, 4370–4379 (1972). Article  CAS  Google


Scholar  * Principi, A., Vignale, G., Carrega, M. & Polini, M. Impact of disorder on Dirac plasmon losses. _Phys. Rev. B_ 88, 121405(R) (2013). Article  Google Scholar  * Principi, A.,


Vignale, G., Carrega, M. & Polini, M. Intrinsic lifetime of Dirac plasmons in graphene. _Phys. Rev. B_ 88, 195405 (2013). Article  Google Scholar  * Li, Z. Q. et al. Dirac charge


dynamics in graphene by infrared spectroscopy. _Nature Phys._ 4, 532–535 (2008). Article  CAS  Google Scholar  * Mak, K. F. et al. Measurement of the optical conductivity of graphene. _Phys.


 Rev. Lett._ 101, 196405 (2008). Article  Google Scholar  * Christensen, J., Manjavacas, A., Thongrattanasiri, S., Koppens, F. H. L. & García de Abajo, F. J. Graphene plasmon waveguiding


and hybridization in individual and paired nanoribbons. _ACS Nano_ 6, 431–440 (2012). Article  CAS  Google Scholar  * Vakil, A. & Engheta, N. Transformation optics using graphene.


_Science_ 332, 1291–1294 (2011). Article  CAS  Google Scholar  * Li, Y. et al. Graphene plasmon enhanced vibrational sensing of surface-adsorbed layers. _Nano Lett._ 14, 1573–1577 (2014).


Article  CAS  Google Scholar  * Nikitin, A. Y., Guinea, F., Garcia-Vidal, F. J. & Martin-Moreno, L. Surface plasmon enhanced absorption and suppressed transmission in periodic arrays of


graphene ribbons. _Phys. Rev. B_ 85, 081405(R) (2012). Article  Google Scholar  * Thongrattanasiri, S., Koppens, F. H. L. & García de Abajo, F. J. Complete optical absorption in


periodically patterned graphene. _Phys. Rev. Lett._ 108, 047401 (2012). Article  Google Scholar  * Gullans, M., Chang, D., Koppens, F. H. L., García de Abajo, F. J. & Lukin, M.


Single-photon nonlinear optics with graphene plasmons. _Phys. Rev. Lett._ 111, 247401 (2013). Article  CAS  Google Scholar  * Huidobro, P. A., Nikitin, A. Y., González-Ballestero, C.,


Martín-Moreno, L. & García-Vidal, F. J. Superradiance mediated by graphene surface plasmons. _Phys. Rev. B_ 85, 155438 (2012). Article  Google Scholar  * Wunsch, B., Stauber, T., Sols,


F. & Guinea, F. Dynamical polarization of graphene at finite doping. _New J. Phys._ 8, 318 (2006). Article  Google Scholar  * Hwang, E. H. & Das Sarma, S. Dielectric function,


screening, and plasmons in two-dimensional graphene. _Phys. Rev. B_ 75, 205418 (2007). Article  Google Scholar  * Principi, A., Polini, M. & Vignale, G. Linear response of doped graphene


sheets to vector potentials. _Phys. Rev. B_ 80, 075418 (2009). Article  Google Scholar  * Cai, Y., Zhang, L., Zeng, Q., Cheng, L. & Xu, Y. Infrared reflectance spectrum of BN calculated


from first principles. _Solid State Commun._ 141, 262–266 (2007). Article  CAS  Google Scholar  Download references ACKNOWLEDGEMENTS It is a great pleasure to thank J. D. Caldwell, J.


García de Abajo, A. Tomadin and L. Levitov for many useful discussions. This work used open source software (www.matplotlib.org, www.python.org). F.H.L.K. acknowledges support by the


Fundacio Cellex Barcelona, the ERC Career integration grant 294056 (GRANOP), the ERC starting grant 307806 (CarbonLight), and support by EU project GRASP (FP7-ICT-2013-613024-GRASP).


F.H.L.K., M.P. and R.H. acknowledge support by the EU under Graphene Flagship (contract no. CNECT-ICT-604391). A.P. and G.V. acknowledge DOE grant DE-FG02-05ER46203 and a Research Board


Grant at the University of Missouri. M.P. and M.C. acknowledge support by the Italian Ministry of Education, Universities and Research (MIUR) through the programme ‘FIRB – Futuro in


Ricerca’, Project PLASMOGRAPH (Grant No. RBFR10M5BT) and Project HybridNanoDev (Grant No. RBFR1236VV). M.P. also acknowledges support by the MIUR through the programme ‘Progetti Premiali


2012’ – Project ABNANOTECH. R.H. acknowledges support by the ERC starting grant 258461 (TERATOMO) and the Spanish Ministry of Economy and Competitiveness (National Project MAT2012-36580).


Y.G. and J.H. acknowledge support from the US Office of Naval Research N00014-13-1-0662. AUTHOR INFORMATION Author notes * Achim Woessner, Mark B. Lundeberg, Yuanda Gao and Frank H. L.


Koppens: These authors contributed equally to this work. AUTHORS AND AFFILIATIONS * ICFO – Institut de Ciències Fotòniques, Mediterranean Technology Park, 08860 Castelldefels (Barcelona),


Spain Achim Woessner, Mark B. Lundeberg & Frank H. L. Koppens * Department of Mechanical Engineering, Columbia University, New York, New York 10027, USA Yuanda Gao & James Hone *


Department of Physics and Astronomy, University of Missouri, Columbia, Missouri 65211, USA Alessandro Principi & Giovanni Vignale * CIC nanoGUNE, 20018 Donostia-San Sebastian, Spain


Pablo Alonso-González * NEST, Istituto Nanoscienze – CNR and Scuola Normale Superiore, 56126 Pisa, Italy Matteo Carrega & Marco Polini * SPIN-CNR, Via Dodecaneso 33, 16146 Genova, Italy


Matteo Carrega * National Institute for Materials Science, 1-1 Namiki, Tsukuba 305-0044, Japan Kenji Watanabe & Takashi Taniguchi * Istituto Italiano di Tecnologia, Graphene Labs, Via


Morego 30 16163 Genova, Italy, Marco Polini * CIC nanoGUNE and UPV/EHU, 20018 Donostia-San Sebastian, Spain Rainer Hillenbrand * IKERBASQUE, Basque Foundation for Science, 48011 Bilbao,


Spain Rainer Hillenbrand Authors * Achim Woessner View author publications You can also search for this author inPubMed Google Scholar * Mark B. Lundeberg View author publications You can


also search for this author inPubMed Google Scholar * Yuanda Gao View author publications You can also search for this author inPubMed Google Scholar * Alessandro Principi View author


publications You can also search for this author inPubMed Google Scholar * Pablo Alonso-González View author publications You can also search for this author inPubMed Google Scholar * Matteo


Carrega View author publications You can also search for this author inPubMed Google Scholar * Kenji Watanabe View author publications You can also search for this author inPubMed Google


Scholar * Takashi Taniguchi View author publications You can also search for this author inPubMed Google Scholar * Giovanni Vignale View author publications You can also search for this


author inPubMed Google Scholar * Marco Polini View author publications You can also search for this author inPubMed Google Scholar * James Hone View author publications You can also search


for this author inPubMed Google Scholar * Rainer Hillenbrand View author publications You can also search for this author inPubMed Google Scholar * Frank H. L. Koppens View author


publications You can also search for this author inPubMed Google Scholar CONTRIBUTIONS A.W. and M.B.L. performed the experiments, discussed the results and wrote the manuscript. Y.G.


fabricated the samples. A.P., M.P., G.V. and M.C. provided the theory on different loss mechanisms. P.A-G. helped with measurements. K.W. and T.T. synthesized the h-BN samples. G.V., M.P.,


J.H., R.H. and F.H.L.K. supervised the work, discussed the results and co-wrote the manuscript. All authors contributed to the scientific discussion and manuscript revisions. CORRESPONDING


AUTHOR Correspondence to Frank H. L. Koppens. ETHICS DECLARATIONS COMPETING INTERESTS R.H. is co-founder of Neaspec GmbH, a company producing scattering-type scanning near-field optical


microscope systems such as the ones used in this study. All other authors declare no competing financial interests. SUPPLEMENTARY INFORMATION SUPPLEMENTARY INFORMATION Supplementary


Information (PDF 1045 kb) RIGHTS AND PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE Woessner, A., Lundeberg, M., Gao, Y. _et al._ Highly confined low-loss plasmons


in graphene–boron nitride heterostructures. _Nature Mater_ 14, 421–425 (2015). https://doi.org/10.1038/nmat4169 Download citation * Received: 03 September 2014 * Accepted: 11 November 2014


* Published: 22 December 2014 * Issue Date: April 2015 * DOI: https://doi.org/10.1038/nmat4169 SHARE THIS ARTICLE Anyone you share the following link with will be able to read this content:


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